A solid AB has NaCl structure. If the radius of cation A is 110 pm, what is the possible radius of anion B ?

A solid AB has NaCl structure. If the radius of cation A is 110 pm, what is the possible radius of anion B ?

Answer:

Given Values

Radius of Cation (r+) = 110 pm

Structure of Solid = NaCl type

NaCl type Means: The radius ratio is between 0.414 – 0.732

Calculations

 \( \frac{Radius~of~Cation}{Radius~of~Anion} \) = 0.414 to 0.732

Calculate the maximum possible radius of Anion ‘B’

 \( \frac{110}{Radius~of~Anion}=0.414 \)

 \( Radius~of~Anion = \frac{110}{0.414} \) = 365.7 pm

Calculate the minimum possible radius of Anion ‘B’

 \( \frac{110}{Radius~of~Anion}=0.732 \)

 \( Radius~of~Anion = \frac{110}{0.732} \) = 150.27 pm

Therefore, the possible radius of anion ‘B’ is 150.27 pm to 365.7 pm

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